8.1 Arrangement of Elements

IGCSE Chemistry Notes – Arrangement of Elements

 

igcse-chemistry-periodic-table
Topic 1

Describe the Periodic Table as an arrangement of elements in periods and groups and in order of increasing proton number / atomic number

Definition

The Periodic Table is a table where elements are arranged in order of increasing atomic number (proton number).
Atomic number = number of protons in the nucleus of an atom.

Periods

  • Horizontal rows in the Periodic Table
  • There are 7 periods
Period number = number of occupied electron shells.
Sodium (Na) / Period 3 / 3 electron shells

Groups

  • Vertical columns in the Periodic Table
  • Elements in the same group have similar chemical properties
For main group elements, group number = number of electrons in the outer shell (valence electrons).
Element Group Outer electrons
Lithium 1 1
Magnesium 2 2
Aluminium 3 3
Chlorine 7 7
Elements are arranged so that similar elements appear in the same column (group). This shows repeating patterns in their chemical and physical properties.
Topic 2

Describe the change from metallic to non-metallic character across a period

Main trend

Across a period, metallic character decreases and non-metallic character increases.
Na , Mg , Al , Si , P , S , Cl , Ar

Trend explanation

Left side Right side
Metals Non-metals
Lose electrons easily Gain electrons easily
Form positive ions Form negative ions
Good conductors Poor conductors
  • Nuclear charge increases
  • Atoms hold electrons more strongly
  • It becomes harder to lose electrons
  • It becomes easier to gain electrons
Topic 3

Describe the relationship between group number and the charge of the ions formed from elements in that group

General rule

Main group elements form ions to obtain a full outer electron shell (noble gas configuration).
Group Ion formed Charge
1 Lose 1 electron +1
2 Lose 2 electrons +2
3 Lose 3 electrons +3
5 Gain 3 electrons -3
6 Gain 2 electrons -2
7 Gain 1 electron -1
0 Do not form ions stable

Sodium (Group 1)

Na  ->  Na+  +  e-

Forms a +1 ion.

Magnesium (Group 2)

Mg  -> Mg2+  +  2e-

Forms a +2 ion.

Chlorine (Group 7)

Cl  +  e-  ->  Cl-

Forms a -1 ion.

Topic 4

Explain similarities in the chemical properties of elements in the same group of the Periodic Table in terms of their electronic configuration

Elements in the same group have similar chemical properties because they have the same number of outer shell electrons.

Example: Group 1 (Alkali Metals)

Element Electron configuration
Lithium 2,1
Sodium 2,8,1
Potassium 2,8,8,1
  • All have 1 outer electron
  • All form +1 ions
  • React vigorously with water
  • Form alkaline solutions

Example: Group 7 (Halogens)

Element Electron configuration
Fluorine 2,7
Chlorine 2,8,7
Bromine 2,8,18,7
  • All have 7 outer electrons
  • All gain 1 electron
  • All form -1 ions
  • React with metals to form salts
Na + Cl ? NaCl
Topic 5

Explain how the position of an element in the Periodic Table can be used to predict its properties

From the group number

  • Number of outer electrons
  • Type of ion formed
  • Type of bonding
  • Reactivity

From the period number

  • Number of electron shells
  • Approximate atomic size

Example prediction: Group 2, Period 3

  • 2 outer electrons
  • Forms a 2+ ion
  • Metal
  • Reacts with acids
  • Forms ionic compounds
This describes Magnesium (Mg).

Example: Element in Group 7

  • Non-metal
  • Forms -1 ions
  • Reactive
  • Forms salts with metals
Topic 6

Supplement – Identify trends in groups, given information about the elements

Example: Group 1 (Alkali Metals)

Property Trend down group
Reactivity Increases
Melting point Decreases
Atomic size Increases
  • Outer electron is further from the nucleus
  • It becomes easier to remove

Example: Group 7 (Halogens)

Property Trend down group
Reactivity Decreases
Melting point Increases
Colour Darker
Exam Summary

Summary of key exam points

Periodic Table is arranged by increasing atomic number
Periods = rows, Groups = columns
Group number = number of outer electrons
Across a period, metallic character decreases
Group number helps predict ion charge
Elements in the same group have similar chemical properties
Position helps predict reactivity and bonding
Trends occur down groups
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